Microwave-assisted one-pot hydrostannylation/Stille couplings.

نویسندگان

  • R E Maleczka
  • J M Lavis
  • D H Clark
  • W P Gallagher
چکیده

In a fraction of the time required by conventional methods, microwave-accelerated one-pot hydrostannylation/Stille coupling allows 1-alkynes to be efficiently transformed into 1,3-dienes or styrenes.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Stille couplings catalytic in tin: the "Sn-O" approach.

A one-pot tandem Pd-catalyzed hydrostannylation/Stille coupling protocol for the stereoselective generation of vinyltins and their subsequent union, employing only catalytic amounts of tin, is described. By recycling the organotin halide Stille byproduct back to organotin hydride, a hydrostannylation/cross-coupling sequence can be carried out with catalytic amounts of tin. Such a process is mos...

متن کامل

Microwave-assisted Synthesis of Acridine-1,8(2H,5H)-diones via a One-pot, Three Component Reaction

A new and improved protocol for the synthesis, in good to excellent yields, of acridine-1,8(2H,5H)-diones is described, involving a one-pot, three component reaction of dimedone, arylglyoxals, and ammonium acetate in water under microwave irradiation.  

متن کامل

Microwave-assisted one-pot synthesis of 1-amidoalkyl 2-naphthols and dibenzo [a,j] xanthenes using phosphorus pentoxide on solid supports

A convenient, efficient and practical procedure for the synthesis of 1-amidoalkyl 2-naphthols is described by condensation of aromatic aldehydes with amides and 2-naphthol in the presence of P2O5/SiO2 as an efficient catalyst. Moreover, in the present of this catalyst, the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes is studied by co...

متن کامل

Microwave-assisted one-pot synthesis of 1-amidoalkyl 2-naphthols and dibenzo [a,j] xanthenes using phosphorus pentoxide on solid supports

A convenient, efficient and practical procedure for the synthesis of 1-amidoalkyl 2-naphthols is described by condensation of aromatic aldehydes with amides and 2-naphthol in the presence of P2O5/SiO2 as an efficient catalyst. Moreover, in the present of this catalyst, the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes is studied by co...

متن کامل

Efficient one-pot, two-step, microwave-assisted procedure for the synthesis of polysubstituted 2-aminoimidazoles.

A microwave-assisted, one-pot, two-step protocol was developed for the construction of polysubstituted 2-aminoimidazoles. This process involves the sequential formation of imidazo[1,2-a]pyrimidinium salts from readily available 2-aminopyrimidines and alpha-bromocarbonyl compounds, followed by opening of the pyrimidine ring with hydrazine. [reaction: see text]

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Organic letters

دوره 2 23  شماره 

صفحات  -

تاریخ انتشار 2000